Study on chiral separation of triazole pesticides by high-performance liquid chromatography
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(1. College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology,Shijiazhuang Hebei 050018, China;2. Colleges of Sciences, Hebei University of Science and Technology,Shijiazhuang Hebei 050018, China;3. College of Bioscience and Bioengineering, Hebei University of Science and Technology,Shijiazhuang Hebei 050018, China;4.School of Chemical Engineering and Techndogy,Hebei University of Technology,Tianjin 300130,China)

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    Abstract:

    The enantioseparation of six triazole chiral pesticides including triadimefon, diniconazole, myclobutanil, flutriafol, paclobutrazol and bitertanol were studied on Chiralcel OD-H and Chiralcel OJ-H chiral columns in the normal-phase HPLC mode. The resolution conditions were optimized on the two chiral columns. The effect of polarity of mobeil phase on separation was discussed. Resolution results of different cellulose chiral stationary phases and chiral recognition mechanism were further evaluated.

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WU Tong, LI Zhao-yang, LI Qiao-ling, ZHANG Bing-zhu, LI Jing-yin, WANG Wei-xiao. Study on chiral separation of triazole pesticides by high-performance liquid chromatography[J]. Journal of Hebei University of Science and Technology,2008,29(4):279-282,291

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History
  • Received:July 02,2008
  • Revised:September 12,2008
  • Adopted:
  • Online: August 19,2013
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