Cu2O基纳米复合材料的设计及其在光催化领域应用的研究进展
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国家自然科学基金(22308084);河北省高等学校科学技术研究项目(ZD2021321)


Research progress on the design of Cu2O based nanocomposite materials and their applications in photocatalysis
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    摘要:

    纳米氧化亚铜(Cu2O)是一种资源丰富、低成本、低毒性且易合成的p型半导体。基于Cu2O的窄带隙和较强的可见光吸收能力,Cu2O基纳米复合材料在光催化领域具有巨大的发展潜力。然而,Cu2O基纳米复合材料仍面临一些挑战,如光生载流子易复合、光催化活性较低、易氧化为CuO及稳定性差等。详细介绍了Cu2O基纳米复合材料的设计合成策略,重点综述了其在光催化环境保护、清洁能源转化和抗菌领域的研究进展。为推动Cu2O基纳米复合材料在这些领域的实际应用,对下一步研究方向提出以下展望:1)开发Cu2O与非贵金属复合的新型材料,实现高效、低成本的光催化应用;2)抑制Cu2O光腐蚀,提升其稳定性;3)深入研究反应机理,探索光催化剂结构和性能之间的关系;4)提高安全性,关注材料的长期稳定性、生物相容性等,开发广谱抑菌新材料。

    Abstract:

    Nano cuprous oxide (Cu2O) is a p-type semiconductor with abundant resources, low cost, low toxicity, and easy synthesis. Based on the narrow band gap and strong visible light absorption ability of Cu2O, Cu2O based nanocomposite materials have great potential for development in the field of photocatalysis. However, Cu2O based nanocomposite materials still face some challenges, such as easy recombination of photo generated carriers, low photocatalytic activity, easy oxidation to CuO, and poor stability. A detailed introduction to the design and synthesis strategies for Cu2O based nanocomposite materials was provided in this paper, with a particular emphasis on their applications in photocatalytic environmental protection, clean energy conversion, and antibacterial properties. To promote the practical application of Cu2O based nanocomposite materials in these fields, prospects for the next research direction have been proposed: 1) developing novel composite materials of Cu2O and non precious metal to achieve efficient and low-cost photocatalytic applications; 2) inhibiting Cu2O photocorrosion and enhancing its stability; 3) thoroughly investigating the reaction mechanism and exploring the relationship between photocatalyst structure and performance; 4) improving safety, focusing on long-term stability and biocompatibility of materials, and developing new broad-spectrum antibacterial materials.

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韩雨荷,王 赛,李文慧,王若鹏,李义磊,卢 琼,安 静. Cu2O基纳米复合材料的设计及其在光催化领域应用的研究进展[J].河北科技大学学报,2025,46(5):561-574

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  • 收稿日期:2024-11-18
  • 最后修改日期:2025-01-21
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  • 在线发布日期: 2025-11-05
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