CdS修饰低密度TiO2纳米棒阵列复合膜的制备及光电性能
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国家自然科学基金(21173065,21603053); 河北省自然科学基金(B2014208062,B2014208066); 河北省科技计划项目(13214413); 河北科技大学博士启动基金(000691, 010087)


Preparation of the composite film based on CdS-modified TiO2 nanorod array with low density and its photoelectrochemical properties
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    摘要:

    为了提高CdS光敏层在TiO2一维纳米棒阵列中的填充率,在TiO2种子层的基础上,采用水热法于FTO导电玻璃表面生长了棒长较短、棒间距较大的低密度TiO2一维纳米棒阵列膜,通过化学浴沉积在TiO2纳米棒表面包覆CdS种子层,以此为基底采用水热法于TiO2一维纳米阵列中生长CdS光敏层。采用SEM,XRD及紫外-可见吸收光谱对不同CdS水热生长时间的TiO2/CdS复合膜结构进行了表征,并对其光电性能进行了研究。结果表明,低密度TiO2纳米棒阵列有利于CdS生长液在阵列中渗入形成完全包覆的CdS种子层,CdS光敏层通过水热过程在整个TiO2纳米棒表面均匀生长,逐渐形成CdS对TiO2纳米棒阵列的完全填充和包覆,并在阵列顶端形成由CdS纳米短棒组成的花状修饰层;CdS的修饰将TiO2一维纳米阵列膜的光吸收拓展至可见光区,水热生长7 h所得到的TiO2/CdS复合膜具有最高光电流。所制备的CdS修饰低密度TiO2纳米棒复合膜在太阳电池器件中具有很好的应用前景。

    Abstract:

    In order to increase the filling ratio of CdS photosensitized layer into the TiO2 array, a low-density TiO2 nanorod array with short-length rods and large rod-interval is prepared based on the TiO2 seed layer-coated FTO conductive glass through hydrothermal process. CdS seed layer is covered onto the TiO2 nanorod by chemical bath deposition. Then CdS photosensitized layer is grown in the TiO2 nanorod array via hydrothermal approach. SEM, XRD, UV-Vis absorption spectra are employed to characterize the TiO2/CdS composite films with different hydrothermal time of CdS. The photoelectrochemical properties of the TiO2/CdS composite film are also studied. The results indicate that the low-density of the TiO2 nanorod array could facilitate the infiltration of the CdS growth solution into the TiO2 array to form the perfect coverage with CdS seed layers. CdS photosensitized layers are homogeneously grown on the whole TiO2 nanorods and gradually filled in the TiO2 array through hydrothermal process. Meanwhile, flower-like CdS modified layers composed with short-length rods are formed at the top of composite film array. The light absorption of the TiO2 nanorod array is extended to the visible region with the CdS modification. The photocurrent of the TiO2/CdS composite film is obtained via 7 h hydrothermal growth of CdS layer. The excellent photoelctrochemical performance of the composite film of CdS modified TiO2 nanorod array with low density reveales its application prospect in solar cells.

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孙 宝,苏子亭,张 赛,郝彦忠,裴 娟,李英品. CdS修饰低密度TiO2纳米棒阵列复合膜的制备及光电性能[J].河北科技大学学报,2018,39(5):470-476

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  • 收稿日期:2018-05-31
  • 最后修改日期:2018-08-03
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  • 在线发布日期: 2018-10-26
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