To optimizethe scheduleof Chinese Super League by establishing the mathematical model can not onlypromotefairness, obtain the humanization designation, but also achieve the aim of savingmileages, resources and protecting environment effectively.Assuming the distance between any two cities was the Baidu map of direct distance, promoting fairness and humanization as well as pursuing the shortest mileage. Wholetraveling distance of 2015 Chinese Super League schedule was optimized based on the improved simulated annealing algorithm and the model was established by Matlab. The results indicated that the whole traveling distance of optimized tournament is 5.022×105 km, which reduced 12.08% compared with that of actual schedule of 2015 Chinese Super League. Furthermore, 14.5 tons of fuel can be saved, 43.9 kg of sulfur dioxide emissions can be reduced, SO₂ contribution can be reduced to 11.11% and 91 467.4 yuan can be saved in the optimized designation.