Al-Ti-C体系自蔓延高温合成TiC的形态演变
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(1.哈尔滨工业大学材料科学与工程学院,黑龙江哈尔滨 150001;2.哈尔滨工程大学材料科学与化学工程学院,黑龙江哈尔滨 150001;3.吉林大学材料科学与工程学院,吉林长春 130025)

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李新林(1968-),男,河北迁安人,副教授,博士,主要从事镁合金及其复合材料强韧化机制方面的研究

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Morphology evolution of TiC particulates formed by self-propagating high-temperature synthesis in Al-Ti-C system
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(1.College of Materials Science and Engineering, Harbin Institute of Technology, Harbin Heilongjiang 150001, China;2.Co-llege of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin Heilongjiang 150001, China;3.College of Materials Science and Engineering, Jilin University, Changchun Jilin 130025, China )

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    摘要:

    利用真空自蔓延加热-加压装置,采用X射线衍射(X-ray diffraction,XRD)、扫描电镜(scanning electron microscope,SEM)及能谱(energy dispersive spectrum,EDS)等分析测试手段,研究了Al含量、粉末粒度及C/Ti(原子比,下同)对Al-Ti-C体系自蔓延点燃温度、产物相组成及TiC形态的影响。结果表明,Al含量对TiC的尺寸影响最大,随着Al含量由20%(质量分数,下同)增加到50%时,TiC颗粒的尺寸由3~5μm减小到0.7~0.8μm。C粉粒度和C/Ti对TiC的形貌影响最大,当C粉粒度小于75μm或C/Ti≥1时,TiC的形貌为近球形;然而当C粉粒度不小于75μm或C/Ti<1时,TiC的形貌为八面体。

    Abstract:

    The effect of Al content, size of powders and reactant C/Ti atomic ratios on ignition temperatures, phase constituents of the self-propagating high-temperature synthesis (SHS) products and morphology of TiC particulates formed by SHS in an Al-Ti-C system was investigated using the heat pressing vacuum apparatus by X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive spectrum (EDS). The results show that Al content plays an important role in determining the size of TiC particles. The size of TiC particles decreases from approximately 3~5μm to 0.7~0.8μm with increasing Al content from 20% to 50% (weight percent). It is also observed that the size of carbon powders and the reactant C/Ti atomic ratios have a greater effect on morphology of TiC particularly. The TiC grains are in the close-to-sphere shape when the size of carbon powders is less than 75μm or C/Ti≥1; while the morphology of TiC turns to octahedron when the size of carbon powders is more than 75μm or C/Ti<1.

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李新林,陈彦宾,杨宝林,姜启川. Al-Ti-C体系自蔓延高温合成TiC的形态演变[J].河北科技大学学报,2010,31(6):572-577

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  • 收稿日期:2010-06-02
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  • 在线发布日期: 2013-08-19
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