By using the solidification/melting model of FLUENT software, the melting and solidification process of the aluminum-silicon alloy in a cylinder heat storage with double wall were simulated numerically. Considering the third kind of boundary condition, the dynamic temperature field distribution and the position of the phase interface change moving with time are obtained. And the melting and solidification duration time is also calculated. The results have important reference value for the numerical simulation of the phase change problem and the design of phase change energy storage device.