富镍三元层状过渡金属氧化物正极材料的改性
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1.北京智行鸿远汽车有限公司;2.河北科技大学理学院

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Modification of Nickel-Rich Ternary Layered Transition Metal Oxides Positive Materials
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    摘要:

    富镍三元层状过渡金属氧化物正极材料因其具有高的比容量、低廉的价格以及对环境友好特性而受到广泛关注。但材料本身具有循环容量衰减、高温稳定性差等原因。这是由于材料发生Li/Ni混排、相变反应、产气、微裂纹、过渡金属溶出、表面结构变化等而引起。围绕近年来富镍三元层状过渡金属氧化物正极材料改性研究的现状,概括总结了包括表面包覆材料的合成、元素掺杂材料的制备、核壳结构材料的开发、浓度梯度材料的设计等优化方法,并对锂离子电池未来的发展进行了展望。正极材料的优化为开发高能量密度的锂离子电池提供了方向

    Abstract:

    Nickel-rich ternary layered transition metal oxide anode materials have attracted extensive attention because of their high specific capacity, low price and environmental friendliness. However, its further application was hindered by its structural instability, fast capacity degradation in high temperature during the cycling. This is caused by Li/Ni mixing, phase transition reaction, gas generation, microcrack, transition metal dissolution and surface structure change. Focusing on the optimization research of nickel-rich ternary layered transition metal oxide cathode materials, the optimization methods including synthesis of surface coating materials, preparation of element-doped materials, preparation of core-shell structural materials, and synthesis of concentration gradient materials. The future development is prospected. The optimization of the cathode material provides a direction for the development of high energy density lithium-ion batteries

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  • 收稿日期:2020-01-10
  • 最后修改日期:2020-01-10
  • 录用日期:2022-04-26
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